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Physical Chemistry

Vapor

Definition and meaning of Vapor in chemistry.

A vapor is the gaseous form of a substance that is normally a liquid or solid at room temperature and standard pressure. Vapors form when molecules escape from the surface through evaporation (from liquids) or sublimation (from solids).

In more detail

Unlike a gas, which is the natural phase of a substance at standard conditions, a vapor is the gaseous form of a substance that exists as liquid or solid under those conditions. All liquids and solids have a characteristic vapor pressure that increases with temperature, indicating their tendency to enter the vapor phase. The equilibrium between a condensed phase (liquid or solid) and its vapor is fundamental to understanding distillation, evaporative cooling, drying processes, and weather phenomena. Vapors can condense back to their original phase when cooled or compressed.

Key facts

FieldPhysical Chemistry
Example substanceWater vapor, H2O
Thermodynamic propertyVapor pressure increases with temperature
Phase behaviorReversible by cooling or compression
Example

Water evaporating from a puddle during a sunny day becomes water vapor, which rises into the atmosphere and can later condense into clouds.

Frequently asked questions

What is the difference between a vapor and a gas?

A gas is the stable phase of a substance at room temperature and pressure, while a vapor is the gaseous form of a liquid or solid under those same conditions.

Does every liquid have a vapor pressure?

Yes, all liquids have vapor pressure at any temperature above absolute zero, though some substances have very low vapor pressures at room temperature.

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