Clear, accurate chemistry definitions 1,517 terms 6 topics 118-element periodic table
General Chemistry

Neutralization

Definition and meaning of Neutralization in chemistry.

Neutralization is a specific chemical reaction occurring between an acidic compound and a basic compound. These two opposing chemicals react quantitatively with each other to produce water and a salt. This balancing process typically brings the pH of the resulting solution much closer to a neutral 7.0.

In more detail

In a standard aqueous neutralization reaction, the active chemicals completely neutralize each other's extreme properties. The positively charged hydrogen ions from the acid combine perfectly with the hydroxide ions from the base. These highly reactive ions join together to form incredibly stable and neutral liquid water molecules.

The remaining spectator ions from the acid and base do not participate in creating the water. Instead, they pair up to form a new ionic compound known generally as a chemical salt. Neutralization is almost always a strongly exothermic process in the chemistry laboratory.

This means the chemical reaction actively releases noticeable heat energy into the surrounding environment. If a strong acid and a strong base react in perfectly matching stoichiometric amounts, the reaction is complete. The final resulting solution will have a perfectly neutral pH of exactly 7.0 at room temperature. However, using weak acids or weak bases will result in slightly skewed final pH values.

Key facts

FieldGeneral Chemistry
General FormulaAcid + Base → Salt + Water
Primary mechanismHydrogen ions combine with hydroxide ions to form liquid water
Typical pH outcomeMoves the final solution pH much closer to a neutral 7.0
EnthalpyAlmost always an exothermic process that releases measurable heat
Chemical byproductThe remaining spectator ions always form a stable ionic salt
Example

A famous neutralization reaction occurs between powerful hydrochloric acid and highly caustic sodium hydroxide. The balanced chemical equation for this specific reaction is HCl + NaOH → NaCl + H2O. The dangerous hydrogen ions and hydroxide ions combine to form completely harmless drinking water. The remaining sodium ions and chloride ions link together to form common table salt. Even though the starting chemicals are extremely corrosive and dangerous, the final products are totally safe. A student mixing these two clear liquids together would instantly feel the glass beaker become very warm. This released heat perfectly demonstrates the highly exothermic nature of a standard neutralization reaction.

Frequently asked questions

Does a standard neutralization reaction always result in a final pH of exactly 7.0?

No, a perfectly neutral pH only occurs when a strong acid reacts completely with a strong base. If a weak acid reacts with a strong base, the resulting salt solution will be slightly basic.

What exactly is a chemical salt in the context of a standard neutralization reaction?

A salt is simply the completely new ionic compound formed by the remaining parts of the acid and base. It contains the positive cation from the base and the negative anion from the acid.

Why does the glass reaction beaker feel very hot during a neutralization experiment?

The formation of new chemical bonds in the liquid water molecules releases a large amount of excess energy. This chemical energy escapes into the surrounding aqueous solution as highly noticeable thermal heat.

Related terms