Clear, accurate chemistry definitions 1,509 terms 6 topics 118-element periodic table
General Chemistry

Hydrolysis

Definition and meaning of Hydrolysis in chemistry.

Hydrolysis is a specific chemical reaction where a large molecule reacts with water. The water molecule acts like a chemical knife to cut the large molecule into smaller pieces. One new piece gains a hydrogen atom, and the other gains a hydroxyl group.

In more detail

Hydrolysis breaks strong covalent bonds by adding the atoms of a water molecule. Chemists classify this specific process as a type of chemical decomposition reaction. This reaction acts as the exact opposite of a typical dehydration synthesis reaction.

In dehydration synthesis, two smaller molecules join together and release water. The process of hydrolysis is extremely important in both human biology and environmental chemistry. The human body uses special proteins called hydrolase enzymes to speed up hydrolysis.

These enzymes break down the complex carbohydrates, proteins, and fats from your food. This turns them into simpler nutrients that your cells can easily absorb and use. Hydrolysis also matters when dealing with normal chemical salts dissolved in water.

Students often assume that all salt solutions have a neutral pH of exactly 7. However, salts made from weak acids or weak bases undergo hydrolysis. The dissolved salt ions actually react with the surrounding water molecules.

This reaction creates extra hydronium ions or hydroxide ions in the solution. This means many common salt solutions are surprisingly acidic or basic.

Key facts

FieldGeneral Chemistry
Reaction typeDecomposition by adding water
Reverse chemical processDehydration synthesis
Required reactantWater (H2O)
Common biological catalystsHydrolase enzymes
Effect on salt solutionsCan change the overall pH
Example

Table sugar is known to scientists as sucrose and has the chemical formula C12H22O11. Sucrose undergoes a hydrolysis reaction when mixed with water and a tiny amount of acid catalyst. The large sucrose molecule splits exactly in half across its central oxygen bond. It consumes one water molecule during this breaking process. This splitting reaction immediately forms two smaller and much simpler sugar molecules called glucose and fructose. Both products share the identical chemical formula C6H12O6. Your digestive system uses this exact same chemical process to digest candy.

Frequently asked questions

How is hydrolysis different from dehydration synthesis?

Hydrolysis breaks a chemical bond by adding a water molecule. Dehydration synthesis forms a new bond by removing a water molecule.

Why can hydrolysis of a salt change a solution's pH?

Certain salt ions pull apart water molecules to create extra hydroxide or hydronium ions. This shifts the overall pH away from neutral.

Does hydrolysis happen naturally without a catalyst?

Yes, it can occur naturally over time. However, catalysts like strong acids, strong bases, or biological enzymes make the reaction happen much faster.

Related terms