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General Chemistry

Single Bond

Definition and meaning of Single Bond in chemistry.

A single bond is a covalent bond formed when two atoms share one pair of electrons.

In more detail

Single bonds are the most common type of covalent bond in chemistry and are represented as a single line between bonded atoms (for example, H-H, C-H, O-H). They consist of a sigma bond formed by direct overlap of atomic orbitals along the internuclear axis. Single bonds allow free rotation around the bond axis, which is important for molecular flexibility. Single bonds are typically weaker in total bond energy than double or triple bonds between the same two atoms. They are found extensively in alkanes, alcohols, ethers, amines, and numerous inorganic compounds.

Key facts

Bond representationSingle line connecting atoms
Electrons sharedOne pair (2 electrons)
Rotational freedomYes, unrestricted rotation allowed
FieldGeneral Chemistry
Example

In water (H2O), two single bonds connect the oxygen atom to each hydrogen atom.

Frequently asked questions

How is a single bond different from a double bond?

A double bond involves two electron pairs and prevents rotation around the bond, while a single bond involves one electron pair and permits free rotation.

What are some common examples of single bonds?

Single bonds are found throughout chemistry, including H-H in hydrogen gas, C-H in methane and other hydrocarbons, O-H in water and alcohols, and C-C in alkanes.

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