Clear, accurate chemistry definitions 1,227 terms 6 topics 118-element periodic table
General Chemistry

Molecular Geometry

Definition and meaning of Molecular Geometry in chemistry.

Molecular geometry is the three-dimensional arrangement of atoms within a molecule. It describes the spatial positions of atoms in relation to each other and the overall shape of the molecule.

In more detail

The geometry of a molecule is determined by the number of bonding electron pairs and lone electron pairs around the central atom, as explained by the Valence Shell Electron Pair Repulsion (VSEPR) theory. These electron pairs repel each other and adopt an arrangement that minimizes this electrostatic repulsion. Molecular geometry significantly influences a substance's physical and chemical properties, including polarity, reactivity, phase of matter, and biological activity. Understanding these 3D shapes is essential for predicting how molecules will interact in complex chemical systems.

Key facts

FieldGeneral Chemistry
Determining theoryVSEPR theory
Important parameterBond angle
Example

The molecular geometry of water (H2O) is bent or V-shaped due to the presence of two bonding pairs and two lone pairs of electrons on the central oxygen atom.

Frequently asked questions

What is the difference between electron geometry and molecular geometry?

Electron geometry considers the arrangement of all electron domains including bonds and lone pairs, while molecular geometry considers only the arrangement of the atoms.

Related terms