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Physical Chemistry

K Capture

Definition and meaning of K Capture in chemistry.

K capture is a type of radioactive decay in which an atomic nucleus captures an inner-shell electron (typically from the K shell), and the electron combines with a proton to produce a neutron and emit an electron neutrino.

In more detail

K capture occurs when a proton-rich nucleus achieves greater stability by absorbing an orbital electron from the atom, usually from the K shell (the innermost electron orbital). The captured electron merges with a proton in the nucleus to form a neutron, while an electron neutrino (νₑ) is simultaneously emitted to conserve lepton number and energy. This process decreases the nucleus's atomic number by one while keeping the mass number constant, since a proton (charge +1, mass ~1) is converted into a neutron (charge 0, mass ~1). K capture is named after the K shell because electrons are most frequently captured from this innermost shell, though capture from higher shells can occur less commonly.

Key facts

FieldPhysical Chemistry
Also calledElectron capture (EC), orbital electron capture
Nuclear changeAtomic number decreases by 1; mass number unchanged
Emitted particleElectron neutrino (νₑ)
Example

Beryllium-7 undergoes K capture to form stable lithium-7: ⁷Be + e⁻ → ⁷Li + νₑ. This decay has a half-life of 53 days and is commonly observed in solar fusion processes.

Frequently asked questions

Why is it called K capture?

The K shell is the innermost electron orbital around the nucleus. Although electrons from higher shells can sometimes be captured, the process is named after the K shell because capture from this shell is most probable.

How does K capture differ from beta-minus decay?

In K capture, an orbital electron is absorbed into the nucleus where it combines with a proton. In beta-minus decay, a neutron in the nucleus decays into a proton, emitting an electron and antineutrino. Both decrease atomic number by one, but they involve opposite processes.