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Organic Chemistry

Chloroethane

Definition and meaning of Chloroethane in chemistry.

Chloroethane is a haloalkane with the formula C2H5Cl (CH3CH2Cl), a colorless, flammable gas at ordinary room temperature that liquefies just below it; it is commonly known by its older name, ethyl chloride.

In more detail

It is prepared industrially by the hydrohalogenation of ethylene with hydrogen chloride, or by the free-radical chlorination of ethane. Because its boiling point (12.3 °C) is below body temperature, liquid chloroethane sprayed onto skin evaporates almost instantly, drawing heat away and producing rapid, intense local cooling. This property makes it useful as a topical anesthetic (vapocoolant spray) for minor medical procedures and sports injuries. It was historically important as a chemical intermediate in the manufacture of tetraethyllead, a leaded-gasoline antiknock additive.

Key facts

FormulaC2H5Cl (CH3CH2Cl)
Boiling Point12.3 °C
Molar Mass64.51 g/mol
FieldOrganic Chemistry
Example

Ethylene gas reacts with hydrogen chloride via electrophilic addition to form chloroethane: CH2=CH2 + HCl → CH3CH2Cl.

Frequently asked questions

Why does chloroethane spray feel cold on the skin?

Its boiling point (12.3 °C) is below skin temperature, so the liquid evaporates almost immediately on contact, absorbing heat from the skin and producing a brief local anesthetic cooling effect.

Is chloroethane the same substance as ethyl chloride?

Yes, ethyl chloride is the traditional common name for chloroethane (CH3CH2Cl), the systematic IUPAC name.