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Analytical Chemistry

AC Arc

Definition and meaning of AC Arc in chemistry.

An AC arc is an alternating-current electrical discharge used as an excitation source in atomic emission spectroscopy. It vaporizes and excites a solid sample so that it emits light characteristic of the elements it contains.

In more detail

Because the current alternates, the arc extinguishes and reignites during each cycle, which spreads the discharge more evenly over the sample and gives better reproducibility than a direct-current arc, though usually with lower sensitivity. AC arcs were once common for qualitative and semi-quantitative elemental analysis but have largely been replaced by the inductively coupled plasma (ICP).

Key facts

TypeAlternating-current discharge
UseExcitation source in emission spectroscopy
Compared withDC arc (more sensitive, less reproducible)
FieldAnalytical instrumentation
Example

An AC arc struck between two graphite electrodes packed with a powdered sample produces light that a spectrometer separates into the emission lines of each element present.

Frequently asked questions

What is an AC arc used for?

It is used to excite solid samples in atomic emission spectroscopy so the elements present emit their characteristic wavelengths of light for analysis.

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