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Physical Chemistry

Reversible Reaction

Definition and meaning of Reversible Reaction in chemistry.

A reversible reaction is a chemical process where products can react together to reform the original reactants. The forward chemical reaction and the reverse chemical reaction happen at the exact same time. It reaches chemical equilibrium when both competing directions run at equal speeds.

In more detail

Many students picture chemical reactions as a simple one-way street. You mix baking soda and vinegar, and you cannot easily get the powders back. That is an irreversible reaction.

However, a reversible reaction acts completely differently. The newly made products do not just sit there safely in the beaker. They immediately start reacting with each other to turn back into the original starting materials.

We draw these unique reactions using a special double arrow pointing in both directions. At first, the forward reaction happens very quickly. As products slowly build up, the reverse reaction starts speeding up.

Eventually, the two opposite reactions match speeds perfectly. This matching point is officially called dynamic equilibrium. The chemical bonds are still actively breaking and forming.

However, the overall visible amount of each chemical stays perfectly frozen. It looks like the reaction has totally stopped to the naked eye. In reality, a frantic molecular dance continues endlessly at the microscopic level. You can actively push this balance left or right by changing the temperature or adding more chemicals.

Key facts

FieldPhysical Chemistry
NotationDouble arrow (⇄)
Example processH2 + I2 ⇄ 2HI
State reachedDynamic equilibrium
Equilibrium ruleForward rate equals reverse rate
Control ruleLe Chatelier's principle
Example

The reaction between hydrogen gas and iodine gas is a classic reversible process. You write it out as H2 + I2 ⇄ 2HI. If you seal these two gases together in a hot glass bulb, they never fully convert into pure hydrogen iodide. At equilibrium, the forward and backward reactions balance exactly. You will always find a steady mixed blend of all three gases locked inside the bulb.

Frequently asked questions

Does equilibrium mean the chemical reaction has finally stopped?

No, it is a dynamic state. The reactions continue at the molecular level, but the amounts of chemicals stay exactly the same.

Are the amounts of reactants and products equal at equilibrium?

No, their amounts do not have to be equal. Only the speeds of the forward and backward reactions must be exactly equal.

How is this different from a normal chemical reaction?

A normal reaction goes mostly in one direction until it runs out of ingredients. A reversible reaction never fully uses up its starting materials.

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